Pat pork chops dry and season both sides with salt, black pepper, garlic powder, paprika, and cayenne if using.
Heat olive oil in a skillet over medium-high heat.
Sear pork chops for 3 minutes per side until golden brown.
Reduce heat to medium, add butter, brown sugar, and Worcestershire sauce, stirring until combined.
Spoon glaze over the pork chops and cook for another 3-4 minutes, or until the internal temperature reaches 145°F (63°C).
Remove from heat and let pork chops rest for 5 minutes before serving.